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Trans-Dichloridobis[diphen-yl(4-vinyl-phen-yl)phosphane-?P]palladium(II).

ABSTRACT: In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3366?(7) and 2.2966?(7)?Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696?(15):0.304?(15) ratio.

SUBMITTER: Meijboom R

PROVIDER: S-EPMC3238597 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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trans-Dichloridobis[diphen-yl(4-vinyl-phen-yl)phosphane-κP]palladium(II).

Meijboom Reinout R

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3366 (7) and 2.2966 (7) Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696 (15):0.304 (15) ratio. ...[more]

PMID: 22199488

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