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Trans-Dichloridobis[diphen-yl(thio-phen-2-yl)phosphane-?P]palladium(II).

ABSTRACT: The title compound, trans-[PdCl(2)(C(16)H(13)PS)(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd-P bond lengths are 2.3387?(11)?Å, as the Pd atom lies on an inversion point, while the Pd-Cl bond lengths are 2.2950?(12)?Å.

SUBMITTER: Burgoyne AR

PROVIDER: S-EPMC3344332 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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trans-Dichloridobis[diphen-yl(thio-phen-2-yl)phosphane-κP]palladium(II).

Burgoyne Andrew R AR Meijboom Reinout R Chiririwa Haleden H Kirsten Leo L

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

The title compound, trans-[PdCl(2)(C(16)H(13)PS)(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd-P bond lengths are 2.3387 (11) Å, as the Pd atom lies on an inversion point, while the Pd-Cl bond lengths are 2.2950 (12) Å. ...[more]

PMID: 22590098

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Project description:The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd-P bond lengths are 2.3343?(5)?Å, as the Pd atom lies on an inversion centre, while the Pd-Cl bond lengths are 2.3017?(4)?Å. The observed structure was found to be closely related to [PdCl(2){P(C(6)H(11))(3)}(2)] [Grushin et al. (1994 ?). Inorg. Chem.33, 4804-4806], [PdBr(2){P(C(6)H(11))(3)}(2)] [Clarke et al. (2003 ?). Dalton Trans. pp. 4393-4394] and [PdCl(2)P(C(6)H(11))(2)(C(7)H(7))}(2)] [Vuoti et al. (2008 ?). Eur. J. Inorg. Chem. pp. 397-407] (C(6)H(11) is cyclo-hexyl and C(7)H(7) is o-tol-yl). One of the cyclo-hexyl rings is disordered with the phenyl ring in a 0.587?(9):413?(9) ratio. Five long-range C-H?Cl inter-actions were observed within the structure.

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