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Bis(2,2'-bipyridine)(pyridin-2-olato)ruthenium(II) hexa-fluorido-phosphate benzene hemisolvate.

ABSTRACT: In the title compound, [Ru(C(5)H(4)NO)(C(10)H(8)N(2))(2)]PF(6)·0.5C(6)H(6), the Ru(2+) cation has a distorted octa-hedral RuN(5)O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiol-ate ligand [Santra et al. (1997 ?). J. Chem. Soc. Dalton Trans. pp. 1387-1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent mol-ecule is situated on a twofold rotation axis.

SUBMITTER: Hamaguchi T

PROVIDER: S-EPMC3238613 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Bis(2,2'-bipyridine)(pyridin-2-olato)ruthenium(II) hexa-fluorido-phosphate benzene hemisolvate.

Hamaguchi Tomohiko T Ando Isao I

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the title compound, [Ru(C(5)H(4)NO)(C(10)H(8)N(2))(2)]PF(6)·0.5C(6)H(6), the Ru(2+) cation has a distorted octa-hedral RuN(5)O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiol-ate ligand [Santra et al. (1997 ▶). J. Chem. Soc. Dalton Trans. pp. 1387-1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent mol-ecule is situated on a twofold rotation axis. ...[more]

PMID: 22199504

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