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ABSTRACT:
SUBMITTER: Garate-Morales JL
PROVIDER: S-EPMC3008139 | biostudies-literature | 2010 Aug
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100821 Pt 9
In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl-methyl-benzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl-imino-meth-yl)quinoline. The dihedral angle between the η(6)-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF(6) (-) anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.75 ...[more]