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Aqua-dicrotonato(di-2-pyridyl-amine)cobalt(II).

ABSTRACT: The Co atom in the title complex, [Co(CH(3)CHCHCOO)(2)(C(10)H(9)N(3))(H(2)O)], has a distorted recta-ngular-pyramidal geometry formed by the chelating dipyridylamine ligand, and two O atoms of monodentate carboxyl-ate groups of two different crotonate anions and a water molecule. The complex forms a three-dimensional supra-molecular network via inter-molecular O-H?O, N-H?O and C-H?O hydrogen-bonding contacts.

SUBMITTER: Wu J 

PROVIDER: S-EPMC2961059 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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Aqua-dicrotonato(di-2-pyridyl-amine)cobalt(II).

Wu Jian J  

Acta crystallographica. Section E, Structure reports online 20080329 Pt 4

The Co atom in the title complex, [Co(CH(3)CHCHCOO)(2)(C(10)H(9)N(3))(H(2)O)], has a distorted recta-ngular-pyramidal geometry formed by the chelating dipyridylamine ligand, and two O atoms of monodentate carboxyl-ate groups of two different crotonate anions and a water molecule. The complex forms a three-dimensional supra-molecular network via inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen-bonding contacts. ...[more]

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