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Catena-Poly[[chlorido(1,10-phenanthro-line)copper(II)]-?-{2-[(1S,3S)-3-acetyl-2,2-dimethyl-cyclo-but-yl]acetato}].

ABSTRACT: The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin-ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl-ate O atom from the pinononate anion, forming a CuN(2)ClO approximate square plane. A symmetry-generated pinononate O atom completes a square-based pyramidal geometry for the copper ion. The bridging 2-(3-acetyl-2,2-dimethyl-cyclo-but-yl)acetate anion leads to chains in the crystal propagating in [001]. Adjacent 1,10-phenanthroline rings form a dihedral angle of 39.4?(2)°.

SUBMITTER: Ma SY 

PROVIDER: S-EPMC3238700 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[chlorido(1,10-phenanthro-line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl-cyclo-but-yl]acetato}].

Ma Shi-Ying SY   Li Yan-Fei YF  

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin-ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl-ate O atom from the pinononate anion, forming a CuN(2)ClO approximate square plane. A symmetry-generated pinononate O atom completes a square-based pyramidal geometry for the copper ion. The bridging 2-(3-acetyl-2,2-dimethyl-cyclo-but-yl)acetate anion leads to chains  ...[more]

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