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Catena-Poly[[bis-(1-ethyl-1H-imidazole-κN)copper(II)]-μ-oxalato-κO,O:O,O].

ABSTRACT: The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octa-hedral CuO(4)N(2) donor set. The Cu⋯Cu separation through the oxalate bridge is 5.620 (5) Å. Both the Cu atoms and the C-C bond of the oxalate bridge are bis-ected by inversion centres.

SUBMITTER: Xu Q

PROVIDER: S-EPMC3246998 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(1-ethyl-1H-imidazole-κN)copper(II)]-μ-oxalato-κO,O:O,O].

Xu Qian Q

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

The title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)](n), is composed of one-dimensional linear chains running parallel to the a axis. In the chain, trans-[Cu(imidazole)(2)](2+) units are sequentially bridged by bis-bidentate oxalate ligands, resulting in an octa-hedral CuO(4)N(2) donor set. The Cu⋯Cu separation through the oxalate bridge is 5.620 (5) Å. Both the Cu atoms and the C-C bond of the oxalate bridge are bis-ected by inversion centres. ...[more]

PMID: 22219818

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