Browse
Submit Data
Databases
API
Help

Dataset Information

28 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[chloridodimethyl-tin(IV)]-?-chloro-acetato-?O:O'].

ABSTRACT: In the title polymeric coordination compound, [Sn(CH(3))(2)(C(2)H(2)ClO(2))Cl](n), the Sn atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions. Adjacent Sn atoms are bridged by the two O atoms of the carboxylate ligand, forming a chain structure along the a-axis direction.

SUBMITTER: Zhang S

PROVIDER: S-EPMC3238711 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[[chloridodimethyl-tin(IV)]-μ-chloro-acetato-κO:O'].

Zhang Shaoliang S Zhang Junhong J Zhang Rufen R

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

In the title polymeric coordination compound, [Sn(CH(3))(2)(C(2)H(2)ClO(2))Cl](n), the Sn atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions. Adjacent Sn atoms are bridged by the two O atoms of the carboxylate ligand, forming a chain structure along the a-axis direction. ...[more]

PMID: 22199588

Similar Datasets

catena-Poly[[trimethyl-tin(IV)]-?-2-(2-chloro-phenyl)-acetato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(8)H(6)ClO(2))](n), the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxyl-ate O atoms of the 2-chloro-phenyl-acetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 2-chloro-phenyl-acetato ligand, forming a chain structure.

| S-EPMC2970316 | biostudies-literature

catena-Poly[[tri-n-butyl-tin(IV)]-?-2-thio-phene-acetato].

Project description:The title compound, [Sn(C(4)H(9))(3)(C(6)H(5)O(2)S)](n), possesses an infinite chain structure. The SnO(2)C(3) centre has a distorted trigonal-bipyramidal geometry (? = 0.145) with the O atoms in the axial positions. Atoms of the thio-phene group S1 and C4 are disordered over two sites The S atom and one C atom, with attached H atom, of the thiophene ring are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

| S-EPMC2919292 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2-(3-thien-yl)acetato].

Project description:The title compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), forms an infinite chain structure parallel to [100]. There are two mol-ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799?(9)/0.201?(9) and 0.618?(7)/0.382?(7), respectively.

| S-EPMC2967881 | biostudies-other

catena-Poly[[tribenzyl-tin(IV)]-μ-2-(piperidin-1-ylcarbothio-ylsulfan-yl)acetato-κO:O'].

Project description:The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl-ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O(covalent) bond by 0.093 (4) Å and in the second mol-ecule, the Sn atom is displaced by 0.105 (4) Å in the same direction.

| S-EPMC2983362 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-quinaldato].

Project description:The title compound, [Sn(CH(3))(3)(C(10)H(6)NO(2))](n), forms an extended one-dimensional chain structure. There are two independent Sn(IV) ions, both of which are in slightly distorted trigonal-bipyramidal coordination environments with two symmetry-related O atoms in the axial sites. In each case, the Sn(IV) ion and one of the three equatorial C atoms lie on a crystallographic twofold axis.

| S-EPMC2914916 | biostudies-literature

catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]{?-[(N,N-diisopropylcar-bamo-thioyl)sulfanyl]acetato-?O:O'}].

Project description:In the title compound, [Sn(C(7)H(6)F)(3)(C(9)H(16)NO(2)S(2))](n), the Sn atom is coordinated in a slightly distorted, trans-C(3)SnO(2) trigonal-bipyramidal environment. Symmetry-related Sn atoms are bridged by diisopropyl-dithio-carbamoylacetato ligands, forming a one-dimensional polymer along [001].

| S-EPMC2983683 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2-phenyl-butano-ato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(10)H(11)O(2))](n), the Sn atom has a distorted trigonal-bipyramidal coordination geometry, with two O atoms of two symmetry-related carboxyl-ate ligands in axial positions and three methyl groups in equatorial positions. In the crystal structure, carboxyl-ate bridges link the metal atoms, forming zigzag chains parallel to the b axis.

| S-EPMC3011523 | biostudies-literature

catena-Poly[[triphenyl-tin(IV)]-?-phenyl-phosphinato-?O:O'].

Project description:In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2) (-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H?? inter-actions, forming a two-dimensional network lying parallel to (001).

| S-EPMC3238605 | biostudies-literature

catena-Poly[[di-tert-butyl-tin(IV)]-μ-oxalato].

Project description:The title compound, [Sn(C4H9)2(C2O4)] n , an unexpected side product in the reaction of di-tert-butyl-tin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn(IV) atom of the one-dimensional coordination polymer is located on a mirror plane and is coordinated by two chelating oxalate ions with two rather different Sn-O bond lengths of 2.150 (1) and 2.425 (1) Å, and two t-butyl groups with Sn-C bond lengths of 2.186 (2) and 2.190 (2) Å. The coordination polyhedron around the Sn(IV) atom is a distorted tetra-gonal disphenoid. The centrosymmetric oxalate ion also has an asymmetric coordination geometry, as reflected by the two slightly different C-O bond lengths of 1.242 (2) and 1.269 (2) Å. The chains of the polymer propagate along the b-axis direction. Only van der Waals inter-actions are observed between the chains.

| S-EPMC3998617 | biostudies-literature

catena-Poly[[aqua-trimethyl-tin(IV)]-{[trimethyl-tin(IV)]-?(3)-thio-phene-2,5-dicarboxyl-ato}].

Project description:In the title compound, [Sn(2)(CH(3))(6)(C(6)H(2)O(4)S)(H(2)O)](n), each of the two crystallographically independent Sn atoms exhibits a distorted trigonal-bipyramidal coordination geometry formed by two O and three C atoms. The coordinated water mol-ecule plays an important role in crystal packing consolidation via O-H?O hydrogen bonding.

| S-EPMC2968262 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data