Browse
Submit Data
Databases
API
Help

Dataset Information

13 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N-Benzyl-P-(2-ethyl-phen-yl)-P-phenyl-phosphinic amide.

ABSTRACT: In the crystal structure of the title compound, C(21)H(22)NOP, the amine H atom is involved in N-H?O hydrogen-bonding inter-actions, resulting in chains along the c axis. The crystal lattice is consolidated by weak inter-molecular C-H?? inter-actions.

SUBMITTER: Kinfe HH

PROVIDER: S-EPMC3239033 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

N-Benzyl-P-(2-ethyl-phen-yl)-P-phenyl-phosphinic amide.

Kinfe Henok H HH Hamese Augustine A Hughes Tanya T Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

In the crystal structure of the title compound, C(21)H(22)NOP, the amine H atom is involved in N-H⋯O hydrogen-bonding inter-actions, resulting in chains along the c axis. The crystal lattice is consolidated by weak inter-molecular C-H⋯π inter-actions. ...[more]

PMID: 22199881

Similar Datasets

N-Ethyl-N-phen-yl{[eth-yl(phen-yl)carbamothio-yl]disulfan-yl}carbothio-amide.

Project description:The asymmetric unit of the title compound, C(18)H(20)N(2)S(4), contains one half-mol-ecule, the complete molecule being generated by a twofold rotation axis. The plane through the NCS(2) group [maximum deviation = 0.01 (7) Å] is orthogonal to the phenyl ring, forming a dihedral angle of 89.4 (3)°. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions.

| S-EPMC3393985 | biostudies-literature

P,P-Bis[4-(dimethyl-amino)-phen-yl]-N,N-bis-(propan-2-yl)phosphinic amide.

Project description:The mol-ecular structure of the title compound, C(22)H(34)N(3)OP, adopts a distorted tetra-hedral geometry at the P atom, with the most noticeable distortion being for the O-P-N angle [117.53?(10)°]. An effective cone angle of 187° was calculated for the compound. In the crystal, weak C-H?O inter-actions create infinite chains along [100], whereas C-H?? inter-actions propagating in [001] generate a herringbone motif.

| S-EPMC3569256 | biostudies-literature

Benz-yl(phen-yl)phosphinic acid.

Project description:The title compound, C(13)H(13)O(2)P, crystallized as enanti-omerically pure crystals; for the crystal measured, the P atom has R stereochemistry. The crystal structure displays O-H⋯O hydrogen bonding, which links individual mol-ecules related by a 2(1) screw axis parallel to the crystallographic a-axis direction into continuous chains.

| S-EPMC3089092 | biostudies-literature

rac-Eth-yl(phen-yl)phosphinic acid.

Project description:The crystal structure of the title compound, C8H11O2P, features O-H?O hydrogen bonds, which link mol-ecules related by the b-glide plane into chains along [010].

| S-EPMC3589060 | biostudies-literature

P-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl-thio-phosphinic amide.

Project description:The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra-hydro-furan. In the solid state, intra-molecular N-H?S hydrogen bonding influences the mol-ecular conformation; a P-N-P-N torsion angle of 2.28?(9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02?(4)°.

| S-EPMC2977763 | biostudies-literature

Dichloro-phosphinic bis-(2-chloro-eth-yl)amide.

Project description:In the title compound, C4H8Cl4NOP, the two chloro-ethyl groups are not related by crystallographic symmetry. The difference in the conformation of the two groups is shown by their N-C-C-Cl torsion angles of 64.57?(15) and 175.62?(10)°.

| S-EPMC3588365 | biostudies-literature

(9H-Fluoren-9-yl)(phen-yl)phosphinic acid.

Project description:The crystal structure of the title compound, C19H15O2P, features pairs of mol-ecules joined by O-H?O hydrogen bonds across crystallographic inversion centers. In addition, ?-? inter-actions, with a centroid-centroid distance of 3.6273?(9)?Å between the fluorene ring systems, connect the dimers into chains along [01-1]. The three rings make dihedral angles of 1.34?(9), 1.52?(10) and 1.51?(7)° with each other.

| S-EPMC3588309 | biostudies-literature

Ethyl [(benzyl-aza-nium-yl)(2-hy-droxy-phen-yl)meth-yl]phospho-nate.

Project description:The title compound, C(16)H(20)NO(4)P, crystallizes as a zwitterion. In the mol-ecule, the two aromatic rings form a dihedral angle of 55.2?(1)°. In the crystal, inter-molecular N-H?O and O-H?O hydrogen bonds link the mol-ecules into columns propagating in [010].

| S-EPMC3213461 | biostudies-literature

rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl-amide-borane hemihydrate.

Project description:In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho-rus atoms shows distortions in their tetra-hedral environments with the cyclo-hexyl substituents disordered over two orientations in a 0.851?(3):0.149?(3) occupancy ratio. The crystal structure is assembled via O-H?O inter-actions between pairs of phosphininc amide mol-ecules and water molecules, creating hydrogen-bonded dimers with graph-set R(2) (4)(8) along [001]. Weak C-H?O inter-actions are also observed.

| S-EPMC3569809 | biostudies-other

N-[(3-Ethyl-phen-yl)carbamo-thio-yl]-2,2-di-phenyl-acetamide.

Project description:In the title mol-ecule, C23H22N2OS, the di-phenyl-acetyl and ethyl-benzene groups adopt a trans-cis conformation, respectively, with respect to the S atom across the (S=)C-N bonds. This conformation is stabilized by an intra-molecular N-H?O hydrogen bond and a weak C-H?S hydrogen bond. The ethyl-substituted benzene ring forms dihedral angles of 87.53?(15) and 73.94?(15)° with the phenyl rings. In the crystal, N-H?O hydrogen bonds link mol-ecules into chains along [100]. A weak C-H?? inter-action is also observed.

| S-EPMC3772456 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data