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Bis[bis-(1H-pyrazol-1-yl)methane-κN,N](formato-κO,O')copper(II) perchlorate.

ABSTRACT: In the crystal structure of the title compound, [Cu(HCO(2))(C(7)H(8)N(4))(2)]ClO(4), the Cu(II) ion is octa-hedrally coordinated by one bidentate formate ion and two bidentate bis-(1H-pyrazol-1-yl)methane ligands. There are C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.487 (3) Å] in the crystal structure. The perchlorate anion is disordered over two positions with an occupancy ratio of 0.628 (9):0.372 (9).

SUBMITTER: Zhao CJ

PROVIDER: S-EPMC3246920 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Bis[bis-(1H-pyrazol-1-yl)methane-κN,N](formato-κO,O')copper(II) perchlorate.

Zhao Cai-Juan CJ Zhang Rui-Feng RF

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

In the crystal structure of the title compound, [Cu(HCO(2))(C(7)H(8)N(4))(2)]ClO(4), the Cu(II) ion is octa-hedrally coordinated by one bidentate formate ion and two bidentate bis-(1H-pyrazol-1-yl)methane ligands. There are C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.487 (3) Å] in the crystal structure. The perchlorate anion is disordered over two positions with an occupancy ratio of 0.628 (9):0.372 (9). ...[more]

PMID: 22219740

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