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Bis[(2-quinol-yl)methane-diol-?N,O](sulfato-?O)copper(II) dihydrate.

ABSTRACT: In the title compound, [Cu(SO(4))(C(10)H(9)NO(2))(2)]·2H(2)O, the Cu(II) ion is chelated by two (2-quinol-yl)methane-diol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal-bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial sites. The dihedral angle between the two essentially planar quinoline ring systems is 45.02?(9)°. In the crystal structure, an extensive O-H?O hydrogen-bonding network forms layers parallel to the ab plane.

SUBMITTER: Martins ND

PROVIDER: S-EPMC2960162 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Bis[(2-quinol-yl)methane-diol-κN,O](sulfato-κO)copper(II) dihydrate.

Martins Nuno D ND Silva Joana A JA Ramos Silva Manuela M Matos Beja Ana A Sobral Abilio J F N AJ

Acta crystallographica. Section E, Structure reports online 20080123 Pt 2

In the title compound, [Cu(SO(4))(C(10)H(9)NO(2))(2)]·2H(2)O, the Cu(II) ion is chelated by two (2-quinol-yl)methane-diol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal-bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial sites. The dihedral angle between the two essentially planar quinoline ring systems is 45.02 (9)°. In the crystal structure, an extensive O-H⋯O hydrogen-bonding network forms layers parallel to the ab pla ...[more]

PMID: 21201345

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