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N'-[Bis(benzyl-sulfan-yl)methyl-idene]benzohydrazide.

ABSTRACT: In the title hydrazonodithio-ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C-N-N-C torsion angle is 139.71?(13)°. The pyridine ring forms dihedral angles of 52.96?(8) and 86.46?(8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42?(9)°]. Supra-molecular chains sustained by N-H?O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C-H?O and C-H?N inter-actions.

SUBMITTER: Tayamon S 

PROVIDER: S-EPMC3379243 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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N'-[Bis(benzyl-sulfan-yl)methyl-idene]benzohydrazide.

Tayamon Shahedeh S   Ravoof Thahira Begum S A TB   Tahir Mohamed Ibrahim Mohamed MI   Crouse Karen A KA   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20120505 Pt 6

In the title hydrazonodithio-ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C-N-N-C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°]. Supra-molecular chains sustained by N-H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consoli  ...[more]

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