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20,23,26,29,32,35,38,41-Octa-oxa-5,9,13-triaza-penta-cyclo-[15.14.10.1.1.1]tetra-tetra-conta-1,3(42),7,9,11(44),15(43),16,18,30-nona-ene-6,12-dione acetone mono-solvate.

ABSTRACT: In the crystal structure of the title compound, C(33)H(39)N(3)O(10)·C(3)H(6)O, the acetone mol-ecule is encapsulated into the cavity of the cryptand and fixed by two N-H?O and one C-H?O hydrogen bond. C-H?O and C-H?N inter-actions link neighbouring cryptands. The dihedral angles between the pyridine ring and the benzene rings are 86.47?(17) and 85.53?(13)°.

SUBMITTER: Pan S

PROVIDER: S-EPMC3254454 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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20,23,26,29,32,35,38,41-Octa-oxa-5,9,13-triaza-penta-cyclo-[15.14.10.1.1.1]tetra-tetra-conta-1,3(42),7,9,11(44),15(43),16,18,30-nona-ene-6,12-dione acetone mono-solvate.

Pan Shaowu S Yang Dengke D Yang Yu Y Jiang Lasheng L

Acta crystallographica. Section E, Structure reports online 20111214 Pt 1

In the crystal structure of the title compound, C(33)H(39)N(3)O(10)·C(3)H(6)O, the acetone mol-ecule is encapsulated into the cavity of the cryptand and fixed by two N-H⋯O and one C-H⋯O hydrogen bond. C-H⋯O and C-H⋯N inter-actions link neighbouring cryptands. The dihedral angles between the pyridine ring and the benzene rings are 86.47 (17) and 85.53 (13)°. ...[more]

PMID: 22259393

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