Ontology highlight
ABSTRACT:
SUBMITTER: Loughrey BT
PROVIDER: S-EPMC3200656 | biostudies-literature | 2011 Sep
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20110811 Pt 9
The title complex, [Ru(C(10)H(15))(C(10)H(13)NO(2))](C(24)H(20)B)·C(3)H(6)O, is related to the analogous O-methyl complex. The average Ru-C distance to the penta-methyl-cyclo-penta-dienyl (Cp*) group is 2.19 (3) Å, and 2.21 (1) Å to the ortho, meta and para C atoms of the arene ring. The Ru-C(ipso) bond length of 2.272 (3) Å is significantly longer, reflecting movement of the Ru atom away from the C atoms with electronegative substituents attached. The amide H atom in the cation forms an inter-m ...[more]