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(?-Isopropyl N-phenyl-carbamate)(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) tetra-phenyl-borate acetone monosolvate.

ABSTRACT: The title complex, [Ru(C(10)H(15))(C(10)H(13)NO(2))](C(24)H(20)B)·C(3)H(6)O, is related to the analogous O-methyl complex. The average Ru-C distance to the penta-methyl-cyclo-penta-dienyl (Cp*) group is 2.19?(3)?Å, and 2.21?(1)?Å to the ortho, meta and para C atoms of the arene ring. The Ru-C(ipso) bond length of 2.272?(3)?Å is significantly longer, reflecting movement of the Ru atom away from the C atoms with electronegative substituents attached. The amide H atom in the cation forms an inter-molecular N-H?O hydrogen bond with the carbonyl O atom of the acetone solvent mol-ecule. A C-H?O inter-action also occurs.

SUBMITTER: Loughrey BT

PROVIDER: S-EPMC3200656 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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(η-Isopropyl N-phenyl-carbamate)(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) tetra-phenyl-borate acetone monosolvate.

Loughrey Bradley T BT Williams Michael L ML Healy Peter C PC

Acta crystallographica. Section E, Structure reports online 20110811 Pt 9

The title complex, [Ru(C(10)H(15))(C(10)H(13)NO(2))](C(24)H(20)B)·C(3)H(6)O, is related to the analogous O-methyl complex. The average Ru-C distance to the penta-methyl-cyclo-penta-dienyl (Cp*) group is 2.19 (3) Å, and 2.21 (1) Å to the ortho, meta and para C atoms of the arene ring. The Ru-C(ipso) bond length of 2.272 (3) Å is significantly longer, reflecting movement of the Ru atom away from the C atoms with electronegative substituents attached. The amide H atom in the cation forms an inter-m ...[more]

PMID: 22058857

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