Reactivity of a stable copper-dioxygen complex.
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ABSTRACT:
SUBMITTER: Iovan DA
PROVIDER: S-EPMC5605793 | biostudies-literature | 2017 Sep
REPOSITORIES: biostudies-literature
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Reactivity of a stable copper-dioxygen complex.
Iovan Diana A DA Wrobel Alexandra T AT McClelland Arthur A AA Scharf Austin B AB Edouard Guy A GA Betley Theodore A TA
Chemical communications (Cambridge, England) 20170901 74
We report the isolation of a room temperature stable dipyrromethene Cu(O<sub>2</sub>) complex featuring a side-on O<sub>2</sub> coordination. Reactivity studies highlight the unique ability of the dioxygen adduct for both hydrogen-atom abstraction and acid/base chemistry towards phenols, demonstrating that side-on superoxide species can be reactive entities. ...[more]
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