Browse
Submit Data
Databases
API
Help

Dataset Information

28 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(E)-N-[3-(Imidazol-1-yl)-1-phenyl-propyl-idene]hydroxyl-amine.

ABSTRACT: The title compound, C(12)H(13)N(3)O, exists in an E configuration with respect to the C=N bond [1.285?(2)?Å]. The imidazole ring forms a dihedral angle of 75.97?(10)° with the phenyl ring. In the crystal, mol-ecules are linked via O-H?N and C-H?N hydrogen bonds into sheets lying parallel to (001). The crystal structure also features C-H?? inter-actions.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3295422 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(E)-N-[3-(Imidazol-1-yl)-1-phenyl-propyl-idene]hydroxyl-amine.

Fun Hoong-Kun HK Quah Ching Kheng CK Attia Mohamed I MI Almutairi Maha S MS Ghoneim Soraya W SW

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

The title compound, C(12)H(13)N(3)O, exists in an E configuration with respect to the C=N bond [1.285 (2) Å]. The imidazole ring forms a dihedral angle of 75.97 (10)° with the phenyl ring. In the crystal, mol-ecules are linked via O-H⋯N and C-H⋯N hydrogen bonds into sheets lying parallel to (001). The crystal structure also features C-H⋯π inter-actions. ...[more]

PMID: 22412533

Similar Datasets

1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl-propyl-idene]amino}-3-(2-methyl-phen-yl)urea.

Project description:In the title compound, C(20)H(21)N(5)O, the conformation about the imine bond [1.289?(3)?Å] is E. Overall, the mol-ecule is disk-shaped with the imidazole ring located above the remainder of the mol-ecule and with the dihedral angles of 10.97?(15) and 12.11?(15)°, respectively, between the imidazole ring and the phenyl and methyl-benzene rings; the dihedral angle between the aromatic rings is 8.17?(14)°. Within the urea unit, the N-H atoms are anti to each other and one of the N-H atoms forms an intra-molecular N-H?N hydrogen bond. Helical supra-molecular chains along [001] are formed via N-H?N(imidazole) hydrogen bonds in the crystal structure. These are connected into a three-dimensional architecture by C-H?O(carbon-yl) and C-H?? inter-actions.

| S-EPMC3379417 | biostudies-literature

N (1)-[(1H-Imidazol-2-yl)methyl-idene]-N (4)-phenyl-benzene-1,4-di-amine.

Project description:The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenyl-enedi-amine rings of 30.66?(4)° and between the planes of the phenyl-enedi-amine and N-phenyl rings of 56.63?(7)°. In the crystal, mol-ecules are connected by N-H?N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C-H?? inter-actions between N-phenyl and imidazole rings and slipped ?-? stacking inter-actions between imidazole rings [centroid-centroid distance = 3.516?(4)?Å] giving an overall two-dimensional layered structure lying parallel to (010).

| S-EPMC4120595 | biostudies-literature

(E)-Benz-yl(1-phenyl-ethyl-idene)amine.

Project description:The title compound, C15H15N, represents an E isomer. The mol-ecule exhibits a minor [9.1?(2)%] disorder with methyl-benzyl-idene and benzyl groups inter-changing their positions. The C=N bond length is 1.292?(2)?Å. The mol-ecular geometry is essentially planar, with the maximal twist of 8.5?(3)° for the benzyl group. The herringbone packing arrangement does not exhibit any ?-stacking inter-actions.

| S-EPMC3793782 | biostudies-literature

Crystal structure of (E)-N-{[3-methyl-1-phenyl-5-(1H-pyrrol-1-yl)-1H-pyrazol-4-yl]methyl-idene}hydroxyl-amine.

Project description:The title compound, C15H14N4O, crystallizes with two mol-ecules in the asymmetric unit with similar conformations (r.m.s. overlay fit for the 20 non-H atoms = 0.175?Å). In the first mol-ecule, the dihedral angles between the planes of the central pyrazole ring and the pendant phenyl and pyrrole rings are 42.69?(8) and 51.88?(6)°, respectively, with corresponding angles of 54.49?(7) and 49.61?(9)°, respectively, in the second mol-ecule. In the crystal, the two mol-ecules, together with their inversion-symmetry counterparts, are linked into tetra-mers by O-H?N hydrogen bonds. The tetra-mers form layers parallel to (211) through pairwise C-H?? inter-actions.

| S-EPMC4257281 | biostudies-literature

Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-?N,N'}samarium(III).

Project description:The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H?Cl hydrogen bonds.

| S-EPMC3297284 | biostudies-literature

[(E)-Oxido(pyridin-2-yl-methyl-idene)amine-?(2)N,N'][(E)-N-(pyridin-2-yl-methyl-idene)hydroxyl-amine-?(2)N,N']silver(I) perchlorate-bis-[(E)-N-(pyridin-2-yl-methyl-idene)hydroxyl-amine-?(2)N,N']silver(I) (1/1).

Project description:In the title salt co-crystal, [Ag(C(6)H(5)N(2)O)(C(6)H(6)N(2)O)]ClO(4)·[Ag(C(6)H(6)N(2)O)(2)], the asymmetric unit comprises a [Ag(LH)(2)](+) cation, a perchlorate anion and a neutral (LH)AgL mol-ecule, where LH is pyridine-2-carboxaldoxime. Both silver-containing species feature N,N'-chelating LH and L ligands, which define an N(4) donor set that is highly distorted [dihedral angles between AgC(2)N(2) chelate rings = 45.7?(3) and 44.3?(2)°, respectively] owing, in part, to the close approach of a neighbouring Ag atom, leading to an argentophilic inter-action [Ag?Ag = 3.1868?(11)?Å]. The mol-ecular conformations are stabilized by intra-molecular O-H?O hydrogen bonds. In the crystal, O-H?O inter-actions lead to supra-molecular chains along [010]. Chains aggregate into layers in the ab plane, defining channels along [100] in which reside the perchlorate anions; the latter are disordered over two overlapped orientations in a 50:50 ratio.

| S-EPMC3344365 | biostudies-literature

Trichloridotris{N-[phen-yl(pyridin-2-yl)methyl-idene]hydroxyl-amine-?(2)N,N'}neodymium(III).

Project description:In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen-yl(pyridin-2-yl)methyl-idene]hydroxyl-amine ligands and three Cl(-) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex mol-ecules are stabilized by intra-molecular O-H?Cl hydrogen bonds.

| S-EPMC3344326 | biostudies-literature

Crystal structure of di-?-iodido-bis-{[1,3-bis-(2,6-diiso-propyl-phen-yl)imidazol-2-yl-idene]lithium}.

Project description:In the title binuclear complex, [Li2(C27H36N2)2I2], the unique Li(I) cation is coordinated by two iodide anions and one yl-idene C atom from a 1,3-bis-(2,6-diiso-propyl-phen-yl)imidazol-2-yl-idene ligand in a distorted trigonal-planar geometry. The two symmetry-related iodide anions bridge two Li(I) cations, forming an inversion dimer in which the Li2I2 plane is nearly perpendicular to the imidazol-2-yl-idene ring, with a dihedral angle of 85.5?(3)°. No hydrogen bonding is observed in the crystal.

| S-EPMC4459370 | biostudies-literature

Crystal structure of (pyridin-2-yl-methyl-idene)(tri-phenyl-meth-yl)amine.

Project description:The title Schiff base compound, C25H20N2, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In both mol-ecules, the imine group is approximately coplanar with the pyridine ring, with N-C-C-N torsion angles of 170.1?(3) and -172.0?(3)?Å. In the crystal, A and B dimers are linked by pairs of C-H?? inter-actions and further C-H?? bonds link the dimers into a three-dimensional network.

| S-EPMC4257176 | biostudies-literature

Poly[[[?3-(E)-N-(pyridin-4-yl-methyl-idene)hy-droxy-laminato-?(3) O:N:N'][?2-(E)-N-(pyridin-4-yl-methyl-idene)hydroxyl-amine-?(2) N:N'][(E)-N-(pyridin-4-yl-methyl-idene-?N)hydroxyl-amine]-disilver(I)] nitrate].

Project description:The title coordination polymer, {[Ag2(C6H5N2O)(C6H6N2O)2]NO3} n , features a deprotonated N-(pyridin-4-yl-methyl-idene)hy-droxy-laminate anion and two neutral N-(pyridin-4-yl-methyl-idene)hydroxyl-amine mol-ecules in the asymmetric unit. The anion connects three Ag(I) atoms through its O and two N-donor atoms. One neutral ligand functions in a monodentate mode; the other functions in a bridging mode, binding though its two N atoms. The coordination geometry of the two independent metal atoms is T-shaped; the manner of bridging gives rise to a layer motif parallel to (100). In the crystal, the nitrate ion is disordered over two positions in a 1:1 ratio, and is sandwiched between adjacent layers. O-H?O hydrogen bonding is present between nitrate ions and layers, and also between adjacent layers.

| S-EPMC3588782 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data