Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(+)-Chlorido[(1,2,3,4-?;?P)-2'-diphenyl-phosphanyl-2-diphenyl-phosphoryl-1,1'-binaphth-yl]rhodium(I) methanol monosolvate.

ABSTRACT: In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2'-bis-(diphenyl-phosphan-yl)-1,1'-binaphthyl (BINAP) ligand in a ?(4) mode, one P atom of the diphenyl-phosphanyl group and one Cl atom. The P=O group does not inter-act with the Rh(I) ion but accepts an O-H?O hydrogen bond from the methanol solvent mol-ecule.

SUBMITTER: Meissner A

PROVIDER: S-EPMC3297224 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(+)-Chlorido[(1,2,3,4-η;κP)-2'-diphenyl-phosphanyl-2-diphenyl-phosphoryl-1,1'-binaphth-yl]rhodium(I) methanol monosolvate.

Meissner Antje A Selle Carmen C Drexler Hans-Joachim HJ Heller Detlef D

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2'-bis-(diphenyl-phosphan-yl)-1,1'-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl-phosphanyl group and one Cl atom. The P=O group does not inter-act with the Rh(I) ion but accepts an O-H⋯O hydrogen bond from the methanol solvent mol-ecule. ...[more]

PMID: 22412414

Similar Datasets

rac-2,2'-Bis(diphenyl-phosphan-yl)-1,1'-binaphth-yl: a racemic diphosphine ligand.

Project description:The asymmetric unit of the title compound, C(44)H(32)P(2), conventionally abbreviated BINAP, is one half of the complete chiral BINAP mol-ecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the mol-ecule in two identical halves; a center of symmetry between mol-ecules further determines the racemic pairs. There are no obvious supra-molecular inter-actions between adjacent BINAP mol-ecules.

| S-EPMC3393302 | biostudies-literature

Tetra-chlorido[(diphenyl-phosphino)diphenyl-phosphine oxide-κO]zirconium(IV) benzene monosolvate.

Project description:In the title centrosymmetric mononuclear Zr(IV) compound, [ZrCl(4){P(O)(C(6)H(5))(2)P(C(6)H(5))(2)}(2)]·C(6)H(6), the central Zr(IV) ion is coordinated by two O atoms from two symmetry-related (diphenyl-phosphino)diphenyl-phosphine ligands and four Cl atoms in a distorted octahedral geometry with the four Cl atoms in the equatorial positions. The mol-ecule lies about a center of inversion and the benzene solvent mol-ecule about another center of inversion. The P=O bond [1.528 (2) Å] is slightly longer than a typical P=O double bond (average 1.500 ).

| S-EPMC2969906 | biostudies-literature

(R,R(Fc),S(Ru))-Chlorido(?-p-cymene){1-[1-(diphenyl-phosphanyl)ethyl]-2-[2-(diphenyl-phosphanyl)phenyl]ferrocene-?P,P'}ruthenium(II) hexa-fluorido-phosphate.

Project description:The asymmetric unit of the title compound, [FeRuCl(C(5)H(5))(C(10)H(14))(C(37)H(31)P(2))]PF(6), contains two independent, geometrically similar Ru(II) complexes of a chiral ferrocenyldiphosphane with piano-stool coordination through the ?(6)-bound p-cymene ligand, two chelating phospho-rus donor atoms, and an exo-oriented chloride ion. The mean bond lengths of the two Ru complexes are Ru-C = 2.276?Å, Ru-P = 2.3816?Å, and Ru-Cl = 2.3924?Å. Both chloride ligands form only intra-molecular C-H?Cl inter-actions. Seven weak inter-molecular C-H?F inter-actions involving mainly arene H atoms consolidate the crystal packing, which reveals an approximate c/2 pseudo-translation relating the two independent Ru complex mol-ecules.

| S-EPMC3201293 | biostudies-literature

rac-cis-Dicarbonyl-chlorido{1-[2-(diphenyl-phosphanyl-κP)benz-yl]-3-(phenyl-κC(1))imidazol-2-yl-idene-κC(2)}ruthenium(II) dichloro-methane monosolvate.

Project description:In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa-hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of inter-est with respect to transfer hydrogenation catalysis and also provides an example of C-H activation behavior in late transition metal complexes. The dichloro-methane solvent mol-ecule is disordered over two sets of sites with an occupancy ratio of 0.873 (14):0.127 (14).

| S-EPMC3435630 | biostudies-literature

2,2'-Bis(all-yloxy)-1,1'-binaphth-yl.

Project description:The complete mol-ecule of the title compound, C(26)H(22)O(2), is generated by a crystallographic twofold rotation axis. The dihedral angle between the planes of the two symmetry-related naphthalene ring systems is 69.05 (4)°, while that between the naphthalene ring system and the allyl plane is 13.7 (2)°. No hydrogen bonds or aromatic π-π stacking inter-actions are observed.

| S-EPMC2977843 | biostudies-literature

4-Diphenyl-phosphanyl-1,5-naphthyridine.

Project description:The asymmetric unit of the title compound, C(20)H(15)N(2)P, contains two independent mol-ecules with similar structures. The 1,5-naphthyridine ring system is nearly planar, with maximum deviations of 0.010?(3) and 0.012?(3)?Å; its mean plane is oriented with respect to the two phenyl rings at 79.69?(12) and 84.00?(10)° in one mol-ecule, and at 74.25?(12) and 82.05?(11)° in the other. The two phenyl rings are twisted with respect to each other with a dihedral angle of 75.96?(14)° in one mol-ecule and 86.30?(13)° in the other.

| S-EPMC3470369 | biostudies-literature

2,2'-Bis(prop-2-yn-yloxy)-1,1'-binaphth-yl.

Project description:In the title compound, C(26)H(18)O(2), the mol-ecule is located on a twofold rotation axis. The two naphthyl ring planes in the mol-ecule are nearly perpendicular to each other [dihedral angle = 82.42 (1)°. No classical hydrogen bonds or aromatic π-π stacking inter-actions were observed.

| S-EPMC2915361 | biostudies-literature

2,2'-Bis(4-nitro-phen-oxy)-1,1'-binaphth-yl.

Project description:The title compound, C(32)H(20)N(2)O(6), was synthesized by the reaction of 1,1'-binaphthyl-2,2'-diol and 4-nitro-phenol in the presence of K(2)CO(3). The two naphthalene systems make a dihedral angle of 73.70 (5)°. The crystal packing involves mol-ecules connected by C-H⋯O hydrogen bonds into a chain along the c axis.

| S-EPMC2961794 | biostudies-literature

Chlorido(8-hy-droxy-quinoline-?N,O)(quinolin-8-olato-?N,O)zinc methanol monosolvate.

Project description:In the title compound, [Zn(C(9)H(6)NO)Cl(C(9)H(7)NO)]·CH(3)OH, the Zn(II) ion is N,O-chelated by both a neutral and a deprotonated quinolin-8-ol ligand, with a chloride ligand in the apical site completing the square-pyramidal coordination geometry. The Zn(II) ion is displaced by 0.586?Å in the direction of the chloride ligand from the atoms forming the square plane. In the crystal, the components are linked by inter-molecular O-H?O hydrogen bonds, generating chains along the b axis.

| S-EPMC3200687 | biostudies-literature

(R)-2,2'-Bis(meth-oxy-meth-oxy)-1,1'-binaphth-yl.

Project description:The asymmetric unit of the title compound, C(24)H(22)O(4), contains two independent mol-ecules in both of which the naphthalene ring systems adopts a transoid arrangement. The dihedral angles between the naphthalene ring system in the two mol-ecules are 83.0 (1) and 89.0 (1)°. There are slight differences in the C(H(3))-O-C(H(2))-O- torsion angles of the eqivalent meth-oxy-meth-oxy groups. In the crystal, weak C-H⋯O hydrogen bonds are present.

| S-EPMC3344493 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data