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ABSTRACT:
SUBMITTER: Schuecker R
PROVIDER: S-EPMC3201293 | biostudies-literature | 2011 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20110914 Pt 10
The asymmetric unit of the title compound, [FeRuCl(C(5)H(5))(C(10)H(14))(C(37)H(31)P(2))]PF(6), contains two independent, geometrically similar Ru(II) complexes of a chiral ferrocenyldiphosphane with piano-stool coordination through the η(6)-bound p-cymene ligand, two chelating phospho-rus donor atoms, and an exo-oriented chloride ion. The mean bond lengths of the two Ru complexes are Ru-C = 2.276 Å, Ru-P = 2.3816 Å, and Ru-Cl = 2.3924 Å. Both chloride ligands form only intra-molecular C-H⋯Cl in ...[more]