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Bis(?-3-nitro-phthalato-?O:O)bis-[(thio-urea-?S)zinc] dihydrate.

ABSTRACT: In the title complex, [Zn(2)(C(8)H(3)NO(6))(2)(CH(4)N(2)S)(4)]·2H(2)O, the carboxyl-ate groups of the 3-nitro-phthalate ligands coordinate in a bis-monodentate mode to the Zn(II) cations. This results in the formation of a centrosymmetric dimer containing two Zn(II) cations with distorted tetra-hedral geometries provided by the O atoms of two different 3-nitro-phthalate dianions and the S atoms of two non-equivalent coordinated thio-urea mol-ecules. The crystal structure exhibits N-H?O and O-H?O hydrogen bonds which link the dimers into a three-dimensional network.

SUBMITTER: Gao HP

PROVIDER: S-EPMC3297227 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Bis(μ-3-nitro-phthalato-κO:O)bis-[(thio-urea-κS)zinc] dihydrate.

Gao Hui-Peng HP Guo Ming-Lin ML

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title complex, [Zn(2)(C(8)H(3)NO(6))(2)(CH(4)N(2)S)(4)]·2H(2)O, the carboxyl-ate groups of the 3-nitro-phthalate ligands coordinate in a bis-monodentate mode to the Zn(II) cations. This results in the formation of a centrosymmetric dimer containing two Zn(II) cations with distorted tetra-hedral geometries provided by the O atoms of two different 3-nitro-phthalate dianions and the S atoms of two non-equivalent coordinated thio-urea mol-ecules. The crystal structure exhibits N-H⋯O and O-H⋯O ...[more]

PMID: 22412417

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