Unknown

Dataset Information

0

(2,2'-Bipyridine-6,6'-dicarboxyl-ato-?N,N',O)(6'-carb-oxy-2,2'-bipyridine-6-carboxyl-ato-?N,N',O)rhodium(III).

ABSTRACT: The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2'-bipyridine-6,6'-dicarb-oxy-lic acid) to form a distorted octa-hedral geometry. Face-to-face ?-stacking inter-actions are observed between inversion-related pyridine rings, with a centroid-to-centroid distance of 3.581?(1)?Å [the perpendicular distance between the rings is 3.3980?(7)?Å]. Inter-molecular O-H?O hydrogen bonds link adjacent mol-ecules into one-dimensional supra-molecular chains along the c axis, while several inter-molecular C-H?O inter-actions are also observed.

SUBMITTER: Wang H 

PROVIDER: S-EPMC3297246 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(2,2'-Bipyridine-6,6'-dicarboxyl-ato-κN,N',O)(6'-carb-oxy-2,2'-bipyridine-6-carboxyl-ato-κN,N',O)rhodium(III).

Wang Huimin H   Gu Xiaojun X   Zhang Bingbing B   Su Haiquan H   Hu Ming M  

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2'-bipyridine-6,6'-dicarb-oxy-lic acid) to form a distorted octa-hedral geometry. Face-to-face π-stacking inter-actions are observed between inversion-related pyridine rings, with a centroid-to-centroid distance of 3.581 (1) Å [the perpendicular distance between the rings is 3.3980 (7) Å]. Inter-molecular O-H⋯O hydrogen b  ...[more]

Similar Datasets

Unknown (2,2'-Bipyridine-6,6'-dicarboxyl-ato-?(3)N,N',O(6))(6'-carb-oxy-2,2'-bipyridine-6-carboxyl-ato-?(3)N,N',O(6))cobalt(III).
| S-EPMC3343819 | biostudies-other
Unknown Diaqua-(2,2'-bipyridine-6,6'-dicarboxyl-ato)nickel(II).
| S-EPMC3120548 | biostudies-literature
Unknown Diaqua-(5-carb-oxy-benzene-1,3-dicarboxyl-ato-κO,O)(6,6'-dimethyl-2,2'-bipyridine-κN,N')nickel(II) hepta-hydrate.
| S-EPMC3200942 | biostudies-literature
Unknown Bis(6'-carb-oxy-2,2'-bipyridine-6-carboxyl-ato-?N,N',O)nickel(II) tetra-hydrate.
| S-EPMC2968579 | biostudies-literature
Unknown Poly[diaqua-bis(2,2'-bipyridine)tris-(?(4)-2,2'-bipyridine-4,4'-dicarboxyl-ato)dineodymium(III)].
| S-EPMC2915173 | biostudies-literature
Unknown Bis-(?-pyridine-2,3-dicarboxyl-ato)bis-[aqua-(3-carb-oxy-pyridine-2-carboxyl-ato)indium(III)] tetra-hydrate.
| S-EPMC3254334 | biostudies-literature
Unknown Diaqua-(5-carb-oxy-benzene-1,3-di-carboxyl-ato-?O)(4,4'-dimethyl-2,2'-bipyridine-?N,N')zinc.
| S-EPMC3120513 | biostudies-literature
Unknown Poly[[bis-(2,2-bipyridine)-bis-[?(6)-5-(carboxyl-atometh-oxy)benzene-1,3-dicarboxyl-ato]trimanganese(II)] monohydrate].
| S-EPMC3051434 | biostudies-literature
Unknown Dimethyl 6,6'-dicyano-2,2'-bipyridine-3,3'-dicarboxyl-ate.
| S-EPMC2977680 | biostudies-literature
Unknown Penta-aqua-(5-carb-oxy-pyridine-2-carboxyl-ato-?N,O)(pyridine-2,5-dicarboxyl-ato-?N,O)cerium(III) tetra-hydrate.
| S-EPMC3254311 | biostudies-literature