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Catena-Poly[bis-(dibenzyl-ammonium) [[dichloridomercurate(II)]-?-sulfato-?O:O']].

ABSTRACT: The structure of the title compound, (C(14)H(16)N)(2)[HgCl(2)(SO(4))], consists of an infinite chain propagating along the c direction, containing Hg(II) ions tetra-coordinated by two bridging O atoms of bis-monodentate sulfate anions and two chloride ligands. In the the crystal, N-H?O hydrogen bonding between the cations and the anionic chains consolidates the packing. The crystal structure was determined from an inversion twin with approximately equal twin domains.

SUBMITTER: Boye MS

PROVIDER: S-EPMC3297281 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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catena-Poly[bis-(dibenzyl-ammonium) [[dichloridomercurate(II)]-μ-sulfato-κO:O']].

Boye Mouhamadou Sembene MS Diasse-Sarr Aminata A Grosjean Arnaud A Guionneau Philippe P

Acta crystallographica. Section E, Structure reports online 20120229 Pt 3

The structure of the title compound, (C(14)H(16)N)(2)[HgCl(2)(SO(4))], consists of an infinite chain propagating along the c direction, containing Hg(II) ions tetra-coordinated by two bridging O atoms of bis-monodentate sulfate anions and two chloride ligands. In the the crystal, N-H⋯O hydrogen bonding between the cations and the anionic chains consolidates the packing. The crystal structure was determined from an inversion twin with approximately equal twin domains. ...[more]

PMID: 22412471

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