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Bis[(E)-N-(pyridin-3-yl-methyl-idene)hydroxyl-amine-?N(1)]silver(I) perchlorate.

ABSTRACT: Each of the ions in the title salt, [Ag(C(6)H(6)N(2)O)(2)]ClO(4), is completed by the application of crystallographic twofold symmetry. The Ag(I) atom is coordinated by two pyridine N atoms in an almost linear fashion [N-Ag-N = 170.0?(2)°], with the T-shaped coordination geometry being completed by a weakly associated perchlorate-O atom. Supra-molecular zigzag chains along [100] mediated by O-H?N hydrogen bonds [as parts of R(2) (2)(6) loops] feature in the crystal packing. The perchlorate O atoms are disordered over two sets of sites in a statistical ratio.

SUBMITTER: Xu J 

PROVIDER: S-EPMC3379077 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Bis[(E)-N-(pyridin-3-yl-methyl-idene)hydroxyl-amine-κN(1)]silver(I) perchlorate.

Xu Jing J   Gao Shan S   Ng Seik Weng SW   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20120505 Pt 6

Each of the ions in the title salt, [Ag(C(6)H(6)N(2)O)(2)]ClO(4), is completed by the application of crystallographic twofold symmetry. The Ag(I) atom is coordinated by two pyridine N atoms in an almost linear fashion [N-Ag-N = 170.0 (2)°], with the T-shaped coordination geometry being completed by a weakly associated perchlorate-O atom. Supra-molecular zigzag chains along [100] mediated by O-H⋯N hydrogen bonds [as parts of R(2) (2)(6) loops] feature in the crystal packing. The perchlorate O ato  ...[more]

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