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Catena-Poly[[diaqua-bis(1H-imidazole-?N(3))cobalt(II)]-?-2,3,5,6-tetra-chloro-tereph-thal-ato-?(2)O(1):O(4)].

ABSTRACT: In the title compound, [Co(C(8)Cl(4)O(4))(C(3)H(4)N(2))(2)(H(2)O)(2)](n), the Co(II) ion displays a distorted octa-hedral coordination geometry with two O atoms from two monodentate tetra-chloro-terephthalate dianions, two N atoms from two imidazole mol-ecules and two O atoms from two water mol-ecules. The Co(II) ions are connected via the tetra-chloro-terephthalate dianions into a chain running along the crystallographic [110] direction. Adjacent chains are linked into a two-dimensional network arranged parallel to (010) by classical N-H?O and O-H?O hydrogen bonds.

SUBMITTER: Zheng CG

PROVIDER: S-EPMC3343789 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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catena-Poly[[diaqua-bis(1H-imidazole-κN(3))cobalt(II)]-μ-2,3,5,6-tetra-chloro-tereph-thal-ato-κ(2)O(1):O(4)].

Zheng Chang-Ge CG Zhang Peng P Li Ping P Zhang Pei-Pei PP

Acta crystallographica. Section E, Structure reports online 20120303 Pt 4

In the title compound, [Co(C(8)Cl(4)O(4))(C(3)H(4)N(2))(2)(H(2)O)(2)](n), the Co(II) ion displays a distorted octa-hedral coordination geometry with two O atoms from two monodentate tetra-chloro-terephthalate dianions, two N atoms from two imidazole mol-ecules and two O atoms from two water mol-ecules. The Co(II) ions are connected via the tetra-chloro-terephthalate dianions into a chain running along the crystallographic [110] direction. Adjacent chains are linked into a two-dimensional network ...[more]

PMID: 22589763

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