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Catena-Poly[[diaqua-(4,4'-trimethyl-ene-dipyridine-?N)cobalt(II)]-?-tereph-thalato-?O:O].

ABSTRACT: The title compound, [Co(C(8)H(4)O(4))(C(13)H(14)N(2))(2)(H(2)O)(2)](n), was obtained by the reaction of CoCl(2), 4,4'-trimethyl-enedipyridine and terephthalic acid in a 1:1:1 ratio. The octa-hedrally coordinated cobalt ions are bridged by 4,4'-trimethyl-enedipyridine ligands, generating a chain. These chains are further linked by O-H?O and O-H?N hydrogen bonds, giving a three-dimensional network.

SUBMITTER: Qi XL

PROVIDER: S-EPMC2968293 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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catena-Poly[[diaqua-(4,4'-trimethyl-ene-dipyridine-κN)cobalt(II)]-μ-tereph-thalato-κO:O].

Qi Xu-Liang XL

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

The title compound, [Co(C(8)H(4)O(4))(C(13)H(14)N(2))(2)(H(2)O)(2)](n), was obtained by the reaction of CoCl(2), 4,4'-trimethyl-enedipyridine and terephthalic acid in a 1:1:1 ratio. The octa-hedrally coordinated cobalt ions are bridged by 4,4'-trimethyl-enedipyridine ligands, generating a chain. These chains are further linked by O-H⋯O and O-H⋯N hydrogen bonds, giving a three-dimensional network. ...[more]

PMID: 21581751

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