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Bis[2-(2-oxoindolin-3-yl-idene)-N-phenylhydrazinecarbothio-amidato-?(3)O,N(2),S]nickel(II) dimethyl-formamide monosolvate.

ABSTRACT: The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex mol-ecule and one disordered dimethyl-formamide solvent mol-ecule. The Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by two N, two O and two S atoms. An intra-molecular C-H?S hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked through inter-molecular N-H?S, N-H?O, C-H?N, C-H?O and C-H?S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C-H?? inter-actions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514?(15):0.486?(15) ratio.

SUBMITTER: Ali AQ

PROVIDER: S-EPMC3344298 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Bis[2-(2-oxoindolin-3-yl-idene)-N-phenylhydrazinecarbothio-amidato-κ(3)O,N(2),S]nickel(II) dimethyl-formamide monosolvate.

Ali Amna Qasem AQ Eltayeb Naser Eltaher NE Teoh Siang Guan SG Salhin Abdussalam A Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20120404 Pt 5

The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex mol-ecule and one disordered dimethyl-formamide solvent mol-ecule. The Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by two N, two O and two S atoms. An intra-molecular C-H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked through inter-molecular N-H⋯S, N-H⋯O, C-H⋯N, C-H⋯O and C-H⋯S hydrogen bonds into infinite two-dimensional network ...[more]

PMID: 22590064

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