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Catena-Poly[[[aqua-[2-(6-chloro-pyridin-3-yl)acetato-?O]sodium]-di-?-aqua] monohydrate].

ABSTRACT: The crystal structure of the title compound, {[Na(C(7)H(5)ClNO(2))(H(2)O)(3)]·H(2)O}(n), features polymeric chains along [010]. The Na(+) cation is octa-hedrally coordinated by four bridging water mol-ecules, a terminal water mol-ecule and an O atom derived from a monodentate carboxyl-ate ligand. Adjacent polyhedra share two O?O edges. The polymeric chains are linked into a three-dimensional network via O-H?O and O-H?N hydrogen bonds.

SUBMITTER: Mi Y

PROVIDER: S-EPMC3344329 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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catena-Poly[[[aqua-[2-(6-chloro-pyridin-3-yl)acetato-κO]sodium]-di-μ-aqua] monohydrate].

Mi Yuwei Y Sun Dezhi D Zeng Suyuan S Yan Nana N

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

The crystal structure of the title compound, {[Na(C(7)H(5)ClNO(2))(H(2)O)(3)]·H(2)O}(n), features polymeric chains along [010]. The Na(+) cation is octa-hedrally coordinated by four bridging water mol-ecules, a terminal water mol-ecule and an O atom derived from a monodentate carboxyl-ate ligand. Adjacent polyhedra share two O⋯O edges. The polymeric chains are linked into a three-dimensional network via O-H⋯O and O-H⋯N hydrogen bonds. ...[more]

PMID: 22590095

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