Ontology highlight
ABSTRACT:
SUBMITTER: Venter GJ
PROVIDER: S-EPMC2972166 | biostudies-literature | 2009 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20091118 Pt 12
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenyl-phosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-mol-ecule, lying about an inversion center, of the acetone solvate. Inter-molecular C-H⋯O hydrogen bonds are observed between a C-H group of the triphenyl-ph ...[more]