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1-Isopropyl-4,7-dimethyl-2,8-dinitro-naphthalene.

ABSTRACT: The title compound, C(15)H(16)N(2)O(4), was synthesized from a mixture of ?-himachalene (2-methyl-ene-6,6,9-trimethyl-bicyclo-[5.4.O(1,7)]undec-8-ene) and ?-himachalene (2,6,6,9-tetra-methyl-bicyclo-[5.4.0(1,7)]undeca-1,8-diene) which were isolated from an oil of the Atlas cedar (Cedrus atlantica). The asymmetric unit contains two independent mol-ecules. In each of the two mol-ecules, two O atoms of one nitro group are disordered over two sets of sites with site-occupancy factors of 0.636?(5):0.364?(5) and 0.832?(5):0.168?(5). The crystal structure features weak C-H?O hydrogen bonds.

SUBMITTER: Chakkar M

PROVIDER: S-EPMC3379451 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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1-Isopropyl-4,7-dimethyl-2,8-dinitro-naphthalene.

Chakkar Mouna M Oughris Najia N Benharref Ahmed A Daran Jean-Claude JC Berraho Moha M

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

The title compound, C(15)H(16)N(2)O(4), was synthesized from a mixture of α-himachalene (2-methyl-ene-6,6,9-trimethyl-bicyclo-[5.4.O(1,7)]undec-8-ene) and β-himachalene (2,6,6,9-tetra-methyl-bicyclo-[5.4.0(1,7)]undeca-1,8-diene) which were isolated from an oil of the Atlas cedar (Cedrus atlantica). The asymmetric unit contains two independent mol-ecules. In each of the two mol-ecules, two O atoms of one nitro group are disordered over two sets of sites with site-occupancy factors of 0.636 (5):0. ...[more]

PMID: 22719649

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