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Regio- and enantioselective hydroamination of dienes by gold(I)/menthol cooperative catalysis.


ABSTRACT: Alcohol is key: regio- and enantioselective hydroamination of 1,3-dienes has been achieved with the dinuclear catalyst (R)-DTBM-SEGPHOS. The rate and selectivity of the reaction are enhanced by alcohol additives like menthol, which coordinates the cationic gold(I) to generate a Brønsted acid that can participate in catalysis. Mbs=p-methoxybenzenesulfonyl.

SUBMITTER: Kanno O 

PROVIDER: S-EPMC3382038 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Regio- and enantioselective hydroamination of dienes by gold(I)/menthol cooperative catalysis.

Kanno Osamu O   Kuriyama Wataru W   Wang Z Jane ZJ   Toste F Dean FD  

Angewandte Chemie (International ed. in English) 20110907 42


Alcohol is key: regio- and enantioselective hydroamination of 1,3-dienes has been achieved with the dinuclear catalyst (R)-DTBM-SEGPHOS. The rate and selectivity of the reaction are enhanced by alcohol additives like menthol, which coordinates the cationic gold(I) to generate a Brønsted acid that can participate in catalysis. Mbs=p-methoxybenzenesulfonyl. ...[more]

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