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Tetra-aqua-bis-[5-(pyridin-3-yl)tetra-zolido-?N?]manganese(II) tetra-hydrate.

ABSTRACT: The title compound, [Mn(C?H?N?)?(H?O)?]·4H?O, was obtained by the solution reaction of MnCl? and 3-(2H-tetra-zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa-hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra-zolide ligands occupying trans positions and four water mol-ecules. In the crystal, the mononuclear complex mol-ecules and solvent water mol-ecules are connected into a three-dimensional framework by O-H?N and O-H?O hydrogen bonds.

SUBMITTER: Qi C

PROVIDER: S-EPMC3393165 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis-[5-(pyridin-3-yl)tetra-zolido-κN⁵]manganese(II) tetra-hydrate.

Qi Chen C He Xiang X Shao Min M Li Ming-Xing MX

Acta crystallographica. Section E, Structure reports online 20120613 Pt 7

The title compound, [Mn(C₆H₄N₅)₂(H₂O)₄]·4H₂O, was obtained by the solution reaction of MnCl₂ and 3-(2H-tetra-zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa-hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra-zolide ligands occupying trans positions and four water mol-ecules. In the crystal, the mononuclear complex mol-ecules and solvent water mol-ecules are connected into a three-dimensional framework by O ...[more]

PMID: 22807733

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