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[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-?P,P']dichloridocadmium(II) dichloro-methane disolvate.

ABSTRACT: In the title complex, [CdFe(C(17)H(14)P)(2)Cl(2)]·2CH(2)Cl(2), the Cd(II) atom has a distorted tetra-hedral coordination geometry by two chloride anions and two P atoms of 1,1'-bis-(diphenyl-phosphan-yl)ferrocene. In the crystal, complex mol-ecules are linked into a three-dimensional network by C-H?Cl hydrogen bonds involving the dichloro-methane solvent mol-ecules.

SUBMITTER: Zhu C

PROVIDER: S-EPMC3011616 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-κP,P']dichloridocadmium(II) dichloro-methane disolvate.

Zhu Chengchen C Yang Liguo L Li Dacheng D

Acta crystallographica. Section E, Structure reports online 20101117 Pt 12

In the title complex, [CdFe(C(17)H(14)P)(2)Cl(2)]·2CH(2)Cl(2), the Cd(II) atom has a distorted tetra-hedral coordination geometry by two chloride anions and two P atoms of 1,1'-bis-(diphenyl-phosphan-yl)ferrocene. In the crystal, complex mol-ecules are linked into a three-dimensional network by C-H⋯Cl hydrogen bonds involving the dichloro-methane solvent mol-ecules. ...[more]

PMID: 21589270

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