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Dicarbon-yl(hexa-methyl-ene-1,3,5,7-tetra-mine-?N(1))(?(5)-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluoridoborate.

ABSTRACT: In the title compound, [Fe(C(10)H(15))(C(6)H(12)N(4))(CO)(2)]BF(4), the arrangement around the Fe(II) atom corresponds to a three-legged piano stool. The penta-methyl-cyclo-penta-dienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of the hexa-methyl-ene-tetra-mine ligand occupy the remaining coordination sites, completing a pseudo-octahedral geometry. Both the complex cation and the BF(4) (-) anion reside on crystallographic mirror planes. The Fe-N bond length is 2.069?(2) and the Fe-Cp*(centroid) distance is 1.7452?(3)?Å.

SUBMITTER: M'thiruaine CM

PROVIDER: S-EPMC3393194 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Dicarbon-yl(hexa-methyl-ene-1,3,5,7-tetra-mine-κN(1))(η(5)-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluoridoborate.

M'thiruaine Cyprian M CM Friedrich Holger B HB Changamu Evans O EO Fernandes Manuel A MA

Acta crystallographica. Section E, Structure reports online 20120616 Pt 7

In the title compound, [Fe(C(10)H(15))(C(6)H(12)N(4))(CO)(2)]BF(4), the arrangement around the Fe(II) atom corresponds to a three-legged piano stool. The penta-methyl-cyclo-penta-dienyl (Cp*) ligand occupies three coordination sites, while two CO ligands and one N atom of the hexa-methyl-ene-tetra-mine ligand occupy the remaining coordination sites, completing a pseudo-octahedral geometry. Both the complex cation and the BF(4) (-) anion reside on crystallographic mirror planes. The Fe-N bond len ...[more]

PMID: 22807762

Similar Datasets

Dicarbon-yl(?(5)-cyclo-penta-dien-yl)(hexa-methyl-enetetra-mine-?N(1))iron(II) tetra-fluoridoborate.

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