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Trans-Acetyl-dicarbon-yl(?(5)-cyclo-penta-dien-yl)(methyl-diphenyl-phosphane)molybdenum(II).


ABSTRACT: The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(13)H(13)P)(CO)(2)], was prepared by reaction of [Mo(CH(3))(C(5)H(5))(CO)(3)] with methyl-diphenyl-phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphane ligands trans to each other. There are several inter-molecular C-H?O hydrogen-bonding inter-actions involving carbonyl and acetyl O atoms as acceptors. A close nearly parallel ?-? inter-action between the cyclo-penta-dienyl plane and the phenyl ring of the phosphane ligand is present, with an angle of 6.4?(1)° between the two least-squares planes. The centroid-to-centroid distance between these groups is 3.772?(3)?Å, and the closest distance between two atoms of these groups is 3.449?(4)?Å. Since each Mo complex is engaged in two of these inter-actions, the complexes form an infinite ?-stack coincident with the a axis.

SUBMITTER: Whited MT 

PROVIDER: S-EPMC3435585 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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trans-Acetyl-dicarbon-yl(η(5)-cyclo-penta-dien-yl)(methyl-diphenyl-phosphane)molybdenum(II).

Whited Matthew T MT   Boerma Joseph W JW   McClellan Michael J MJ   Padilla Christian E CE   Janzen Daron E DE  

Acta crystallographica. Section E, Structure reports online 20120808 Pt 9


The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(13)H(13)P)(CO)(2)], was prepared by reaction of [Mo(CH(3))(C(5)H(5))(CO)(3)] with methyl-diphenyl-phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphane ligands trans to each other. There are several inter-molecular C-H⋯O hydrogen-bonding inter-actions involving carbonyl and acetyl O atoms as acceptors. A close nearly parallel π-π inter-action between the cyclo-penta-dienyl plane and the phe  ...[more]

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