Ontology highlight
ABSTRACT:
SUBMITTER: Whited MT
PROVIDER: S-EPMC3435585 | biostudies-literature | 2012 Sep
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20120808 Pt 9
The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(13)H(13)P)(CO)(2)], was prepared by reaction of [Mo(CH(3))(C(5)H(5))(CO)(3)] with methyl-diphenyl-phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphane ligands trans to each other. There are several inter-molecular C-H⋯O hydrogen-bonding inter-actions involving carbonyl and acetyl O atoms as acceptors. A close nearly parallel π-π inter-action between the cyclo-penta-dienyl plane and the phe ...[more]