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(Ethyl-enediamine-?(2)N,N)bis[2-(pyridin-2-yl-?N)-1,3-imidazol-1-ido-?N(1)]cobalt(III) nitrate monohydrate.

ABSTRACT: In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethyl-enediamine in a distorted octa-hedral geometry. In the crystal, classical N-H?N(O) and O-H?N(O) hydrogen bonds connect all the isolated components together to yield a three-dimensional structure.

SUBMITTER: Feng XL

PROVIDER: S-EPMC3435583 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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(Ethyl-enediamine-κ(2)N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN(1)]cobalt(III) nitrate monohydrate.

Feng Xiu-Ling XL Zhang Yu-Ping YP

Acta crystallographica. Section E, Structure reports online 20120808 Pt 9

In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethyl-enediamine in a distorted octa-hedral geometry. In the crystal, classical N-H⋯N(O) and O-H⋯N(O) hydrogen bonds connect all the isolated components together to yield a three-dimensional structure. ...[more]

PMID: 22969456

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