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Poly[(?(5)-2,2'-bipyridine-5,5'-dicarboxyl-ato)lead(II)].

ABSTRACT: In the title polymeric compound, [Pb(C(12)H(6)N(2)O(4))](n), the Pb(II) cation, located on a mirror plane, is N,N'-chelated by a 2-2'-bipyridine-5,5'-dicarboxyl-ate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N(2)O(6) geometry. The carboxylate groups bridge the Pb(II) cations, forming a three-dimensional polymeric structure. The carboxyl-ate group is twisted away from the attached pyridine ring by 11.4?(3)°.

SUBMITTER: Sertcelik M 

PROVIDER: S-EPMC3435613 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Poly[(μ(5)-2,2'-bipyridine-5,5'-dicarboxyl-ato)lead(II)].

Sertçelik Mustafa M   Caylak Delibaş Nagihan N   Cevik Sabri S   Necefoğlu Hacali H   Hökelek Tuncer T  

Acta crystallographica. Section E, Structure reports online 20120823 Pt 9

In the title polymeric compound, [Pb(C(12)H(6)N(2)O(4))](n), the Pb(II) cation, located on a mirror plane, is N,N'-chelated by a 2-2'-bipyridine-5,5'-dicarboxyl-ate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N(2)O(6) geometry. The carboxylate groups bridge the Pb(II) cations, forming a three-dimensional polymeric structure. The carboxyl-ate group is twisted away from the attached pyridine ring by 11.4 (3)°. ...[more]

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