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Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-?N(3))methanol]manganese(I) trifluoromethanesulfonate.

ABSTRACT: In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octa-hedral geometry. The three CO ligands have C-Mn-C angles in the range 89.44?(10)-92.31?(9)°, while the three N atoms of the tripodal ligand form significantly smaller N-Mn-N angles of 82.76?(2)-85.51?(6)°. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoro-methane-sulfonate counter anion is connected by a medium-strength O-H?O hydrogen bond to the hydroxyl group of the manganese complex.

SUBMITTER: Reiss GJ

PROVIDER: S-EPMC3435617 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Tricarbonyl[tris(1-methyl-1H-imidazol-2-yl-κN(3))methanol]manganese(I) trifluoromethanesulfonate.

Reiss Guido J GJ Kunz Peter C PC

Acta crystallographica. Section E, Structure reports online 20120823 Pt 9

In the title compound, [Mn(C(13)H(16)N(6)O)(CO)(3)](CF(3)O(3)S), the Mn(I) atom has a slightly distorted octa-hedral geometry. The three CO ligands have C-Mn-C angles in the range 89.44 (10)-92.31 (9)°, while the three N atoms of the tripodal ligand form significantly smaller N-Mn-N angles of 82.76 (2)-85.51 (6)°. The three N atoms of the tripodal ligand and the three carbonyl ligands coordinate facially. In the crystal, the trifluoro-methane-sulfonate counter anion is connected by a medium-stre ...[more]

PMID: 22969490

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