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Diaqua-bis-[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-?N)nicotinato-?N]manganese(II).

ABSTRACT: In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol-ecules in a distorted octa-hedral environment. Inter-molecular O-H?O hydrogen bonds lead to a chain along [010]. Intra-molecular N-H?O and O-H?O hydrogen bonds are observed.

SUBMITTER: Gao P

PROVIDER: S-EPMC3011436 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Diaqua-bis-[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN)nicotinato-κN]manganese(II).

Gao Peng P Liu Ji-Zhong JZ Zhang Zhong Z Huang Zhong-Jing ZJ

Acta crystallographica. Section E, Structure reports online 20101127 Pt 12

In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol-ecules in a distorted octa-hedral environment. Inter-molecular O-H⋯O hydrogen bonds lead to a chain along [010]. Intra-molecular N-H⋯O and O-H⋯O hydrogen bonds are observed. ...[more]

PMID: 21589328

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