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Pd-catalyzed C-H fluorination with nucleophilic fluoride.

ABSTRACT: The palladium-catalyzed C-H fluorination of 8-methylquinoline derivatives with nucleophilic fluoride is reported. This transformation involves the use of AgF as the fluoride source in combination with a hypervalent iodine oxidant. Both the scope and mechanism of the reaction are discussed.

SUBMITTER: McMurtrey KB 

PROVIDER: S-EPMC3449219 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Pd-catalyzed C-H fluorination with nucleophilic fluoride.

McMurtrey Kate B KB   Racowski Joy M JM   Sanford Melanie S MS  

Organic letters 20120730 16

The palladium-catalyzed C-H fluorination of 8-methylquinoline derivatives with nucleophilic fluoride is reported. This transformation involves the use of AgF as the fluoride source in combination with a hypervalent iodine oxidant. Both the scope and mechanism of the reaction are discussed. ...[more]

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