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6-(4-Meth-oxy-phen-yl)-1,3,5-triazine-2,4-diamine.

ABSTRACT: In the title compound, C(10)H(11)N(5)O, the triazine ring forms a dihedral angle of 10.37?(4)° with the benzene ring. In the crystal, adjacent mol-ecules are linked by a pair of N-H?N hydrogen bonds, forming an inversion dimer with an R(2) (2)(8) ring motif. The dimers are further connected via N-H?O and N-H?N hydrogen bonds, resulting in a three-dimensional network.

SUBMITTER: Thanigaimani K

PROVIDER: S-EPMC3470258 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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6-(4-Meth-oxy-phen-yl)-1,3,5-triazine-2,4-diamine.

Thanigaimani Kaliyaperumal K Razak Ibrahim Abdul IA Arshad Suhana S Jagatheesan Rathinavel R Santhanaraj K Joseph KJ

Acta crystallographica. Section E, Structure reports online 20120908 Pt 10

In the title compound, C(10)H(11)N(5)O, the triazine ring forms a dihedral angle of 10.37 (4)° with the benzene ring. In the crystal, adjacent mol-ecules are linked by a pair of N-H⋯N hydrogen bonds, forming an inversion dimer with an R(2) (2)(8) ring motif. The dimers are further connected via N-H⋯O and N-H⋯N hydrogen bonds, resulting in a three-dimensional network. ...[more]

PMID: 23125702

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Project description:The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-meth-oxy-phen-yl)-1,3,5-triazine mol-ecule and one-half mol-ecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89?(4)° with the adjacent benzene ring. In the crystal, the components are linked by N-H?O and O-H?N hydrogen bonds, thus generating a centrosymmetric 2 + 1 unit of triazine and adipic acid mol-ecules with R(2) (2)(8) motifs. The triazine mol-ecules are connected to each other by N-H?N hydrogen bonds, forming an R(2) (2)(8) motif and a supra-molecular ribbon along the c axis. The 2 + 1 units and the supra-molecular ribbons are further inter-linked by weak N-H?O, C-H?O and C-H?? inter-actions, resulting in a three-dimensional network.

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Project description:Two virtually superimposable mol-ecules comprise the asymmetric unit of the title compound, C(27)H(27)N(3). The range of dihedral angles between the central 1,3,5-triazine ring and the attached benzene rings is 20.88?(14)-31.36?(14)°, and the shape of each mol-ecule is of a flattened bowl. The crystal packing features weak C-H?? bonds and ?-? inter-actions between triazine and benzene rings [centroid-centroid separations = 3.7696?(17) and 3.7800?(18)?Å] that result in the formation of supra-molecular layers in the ac plane. The crystal studied was a non-merohedral twin with a minor twin component of 20.7?(3)%.

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Project description:The complete mol-ecule of the title compound, C24H21N3O6, is generated by the application of threefold rotation symmetry about an axis perpendicular to the central ring. The mol-ecule exhibits a propeller-like shape. The dihedral angle between each benzene ring and the heterocyclic ring is 74.0 (1)°. The mol-ecules pack with no specific inter-molecular inter-actions between them. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155] was used to model disordered solvent mol-ecules, presumed to be acetone; the calculated unit-cell data do not take into account the presence of these.

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Project description:The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N(2),N(2),N(4),N(4)-tetra-ethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitro-phen-yl)ethanone in ethanol at room temperature. The mol-ecular conformation is stabilized by intra-molecular C-H?N hydrogen-bonding inter-actions. There are also inter-molecular N-H?O hydrogen bonds, and C-H?? and ?-? inter-actions, which help to stabilize the crystal structure. The centroid-centroid distance is 3.6172?(10)?Å between adjacent benzene and 1,3,5-triazine rings.

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6-(4-Methyl-phen-yl)-1,3,5-triazine-2,4-di-amine-benzoic acid (1/1).

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3-(2,4-Dichloro-phen-oxy)-1-(4-meth-oxy-phen-yl)-4-(3-nitro-phen-yl)azetidin-2-one.

Project description:In the title compound, C(22)H(16)Cl(2)N(2)O(5), the nearly planar four-membered ?-lactam ring [maximum deviations of 0.011?(2) for the N atom] makes dihedral angles of 68.34?(13), 83.04?(13) and 3.37?(13)° with the dichloro-, nitro- and meth-oxy-phenyl rings, respectively. The crystal structure is stabilized by C-H?O hydrogen-bond inter-actions. In addition, a ?-? stacking inter-action [centroid-centroid distance = 3.6622?(12)?Å] is observed between the ?-lactam and nitro-phenyl rings.

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