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N,N,N,N-Tetra-ethyl-6-{2-[(E)-1-(4-nitro-phen-yl)ethyl-idene]hydrazino}-1,3,5-triazine-2,4-diamine.

ABSTRACT: The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N(2),N(2),N(4),N(4)-tetra-ethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitro-phen-yl)ethanone in ethanol at room temperature. The mol-ecular conformation is stabilized by intra-molecular C-H?N hydrogen-bonding inter-actions. There are also inter-molecular N-H?O hydrogen bonds, and C-H?? and ?-? inter-actions, which help to stabilize the crystal structure. The centroid-centroid distance is 3.6172?(10)?Å between adjacent benzene and 1,3,5-triazine rings.

SUBMITTER: Pan XR

PROVIDER: S-EPMC2977253 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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N,N,N,N-Tetra-ethyl-6-{2-[(E)-1-(4-nitro-phen-yl)ethyl-idene]hydrazino}-1,3,5-triazine-2,4-diamine.

Pan Xiao-Ru XR Jian Fang-Fang FF

Acta crystallographica. Section E, Structure reports online 20090711 Pt 8

The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N(2),N(2),N(4),N(4)-tetra-ethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitro-phen-yl)ethanone in ethanol at room temperature. The mol-ecular conformation is stabilized by intra-molecular C-H⋯N hydrogen-bonding inter-actions. There are also inter-molecular N-H⋯O hydrogen bonds, and C-H⋯π and π-π inter-actions, which help to stabilize the crystal structure. The centroid-centroid distance is 3.6172 (10) Å between adjac ...[more]

PMID: 21583544

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