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Trans-Dichloridobis(4-nitro-aniline-?N(1))palladium(II).

ABSTRACT: In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H?Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H?O and N-H?Cl hydrogen bonds.

SUBMITTER: Feng TJ

PROVIDER: S-EPMC3515110 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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trans-Dichloridobis(4-nitro-aniline-κN(1))palladium(II).

Feng Tian-Jun TJ

Acta crystallographica. Section E, Structure reports online 20121013 Pt 11

In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H⋯O and N-H⋯Cl hydrogen bonds. ...[more]

PMID: 23284337

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