Browse
Submit Data
Databases
API
Help

Dataset Information

25 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Trans-Dichloridobis(2,4-dimethyl-aniline-?N)palladium(II).

ABSTRACT: In the title compound, [PdCl(2)(C(8)H(11)N)(2)], the Pd(II) atom is located on a crystallographic inversion center and adopts a square-planar coordination geometry, with pairs of equivalent ligands in trans positions. In the crystal, adjacent mol-ecules are linked with each other through weak N-H?Cl hydrogen bonds and ?-? stacking inter-actions between the phenyl rings [shortest centroid-centroid distance = 3.720?(2)?Å], leading to the formation of layers parallel to the a-axis direction.

SUBMITTER: Pan Y

PROVIDER: S-EPMC3344335 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

trans-Dichloridobis(2,4-dimethyl-aniline-κN)palladium(II).

Pan Yong Y Guo Hai-Fu HF Ma De-Yun DY Lu Kuan K

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

In the title compound, [PdCl(2)(C(8)H(11)N)(2)], the Pd(II) atom is located on a crystallographic inversion center and adopts a square-planar coordination geometry, with pairs of equivalent ligands in trans positions. In the crystal, adjacent mol-ecules are linked with each other through weak N-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the phenyl rings [shortest centroid-centroid distance = 3.720 (2) Å], leading to the formation of layers parallel to the a-axis direction. ...[more]

PMID: 22590101

Similar Datasets

trans-Dichloridobis(4-methoxy-aniline-?N)palladium(II).

Project description:In the title compound, [PdCl(2)(C(7)H(9)NO)(2)], the Pd atom is situated on a crystallographic centre of inversion. The coordination environment of the Pd atom shows a slightly distorted square-planar geometry. The crystal structure exhibits weak inter-molecular Pd?Cl inter-actions, with Pd?Cl distances of 3.6912?(6)?Å. A chain-like arrangement of mol-ecules realized by inter-molecular N-H?Cl hydrogen bonds is observed along [010].

| S-EPMC2969670 | biostudies-literature

trans-Dichloridobis(2-methyl-aniline-κN)palladium(II).

Project description:In the title compound, [PdCl(2)(C(7)H(9)N)(2)], the Pd atom is situated on an inversion centre and displays a distorted square-planar coordination environment. The crystal structure displays weak inter-molecular N-H⋯Cl hydrogen bonding.

| S-EPMC2968883 | biostudies-literature

trans-Dichloridobis(4-nitro-aniline-?N(1))palladium(II).

Project description:In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H?Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H?O and N-H?Cl hydrogen bonds.

| S-EPMC3515110 | biostudies-literature

trans-Dichloridobis(triphenyl-phosphine)palladium(II).

Project description:The title compound, [PdCl(2){P(C(6)H(5))(3)}(2)], has a slightly distorted square-planar geometry, with the chloride ligands coordinated in a trans configuration. The Pd atom is located on a centre of inversion.

| S-EPMC2961313 | biostudies-literature

trans-Dichloridobis[(pyridin-4-yl)boronic acid-?N]palladium(II) dimethyl sulfoxide disolvate.

Project description:In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd-N and Pd-Cl distances are 2.023?(2) and 2.2977?(7)?Å, respectively, and the average N-Pd-Cl angle is 90°. The dimethyl sulfoxide solvent mol-ecules play a key role in the crystal structure by bridging the complex mol-ecules via O-H?O hydrogen bonds, forming tapes running along the b axis. C-H?O inter-actions also contribute to the cohesion of the crystal.

| S-EPMC3089363 | biostudies-literature

trans-Dichloridobis(triisopropyl-phosphine-?P)palladium(II).

Project description:The title compound, [PdCl(2)(C(9)H(21)P)(2)], is a centrosymmetric mononuclear palladium(II) complex. The Pd(II) atom, which lies on an inversion center, is in a square-planar geometry.

| S-EPMC2961642 | biostudies-literature

trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane}palladium(II).

Project description:The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3550?(7) and 2.2906?(7)?Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two ?-stacked rings of 3.505?(3)?Å. Intra- and intermolecular C-H?Cl hydrogen bonds also occur.

| S-EPMC3009084 | biostudies-other

trans-Dichloridobis(quinoline-?N)palladium(II).

Project description:In the title complex, [PdCl(2)(C(9)H(7)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment defined by two N atoms from two quinoline ligands and two Cl(-) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex; the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and quinoline ligand is 85.63?(8)°. In the crystal, the complex mol-ecules are stacked into columns along the b axis. In the columns, several inter-molecular ?-? inter-actions between the six-membered rings are present, the shortest ring centroid-centroid distance being 3.764?(3)?Å between pyridine rings.

| S-EPMC3274877 | biostudies-other

trans-Dichloridobis(4-phenyl-pyridine-κN)palladium(II).

Project description:The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol-ecule generated by the application of a twofold rotation axis; the N-Pd-N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl-pyridine ligands and two Cl(-) anions. In the refinement, the pyridine ring and the phenyl ring were found to be disordered over two sites with the site-occupancy factors being 0.53 (2) and 0.51 (1), respectively, for the major components.

| S-EPMC3238776 | biostudies-literature

trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II).

Project description:The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], shows a nearly square-planar geometry for the Pd(II) atom within the Cl(2)Pd[P(PhOMe)(3)](2) ligand set. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one Pd(II) atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand.

| S-EPMC2971166 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data