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Trans-Dichloridobis(4-phenyl-pyridine-?N)palladium(II).

ABSTRACT: The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol-ecule generated by the application of a twofold rotation axis; the N-Pd-N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl-pyridine ligands and two Cl(-) anions. In the refinement, the pyridine ring and the phenyl ring were found to be disordered over two sites with the site-occupancy factors being 0.53?(2) and 0.51?(1), respectively, for the major components.

SUBMITTER: Ha K 

PROVIDER: S-EPMC3238776 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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trans-Dichloridobis(4-phenyl-pyridine-κN)palladium(II).

Ha Kwang K  

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol-ecule generated by the application of a twofold rotation axis; the N-Pd-N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl-pyridine ligands and two Cl(-) anions. In the refinement, the pyridine ring and the phenyl ring were found to be disordered over two sites with the site  ...[more]

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