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Potassium N-bromo-2-nitro-benzene-sulfonamidate monohydrate.

ABSTRACT: In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(-)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol-ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene-sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene-sulfonamidate anions. The S-N distance of 1.576?(4)?Å is consistent with an S=N double bond. The crystal structure is stabilized by inter-molecular O-H?N and O-H?Br hydrogen bonds which link the molecules into polymeric layers running parallel to the bc plane.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC3515114 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Potassium N-bromo-2-nitro-benzene-sulfonamidate monohydrate.

Gowda B Thimme BT Foro Sabine S Spandana H S HS

Acta crystallographica. Section E, Structure reports online 20121013 Pt 11

In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(-)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol-ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene-sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene-sulfonamidate anions. The S-N distance of 1.576 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter-molecular O-H⋯N and O-H⋯Br hydrogen bonds which link the molecules into polymeric la ...[more]

PMID: 23284341

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