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Potassium N-bromo-4-chloro-2-methyl-benzene-sulfonamidate monohydrate.

ABSTRACT: In the title compound, K(+)·C7H6BrClNO2S(-)·H2O, the K(+) cation is hepta-coordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methyl-benzene-sulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584?(3)?Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O-H?Br and O-H?N hydrogen bonds.

SUBMITTER: Spandana HS

PROVIDER: S-EPMC3772410 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Potassium N-bromo-4-chloro-2-methyl-benzene-sulfonamidate monohydrate.

Spandana H S HS Foro Sabine S Gowda B Thimme BT

Acta crystallographica. Section E, Structure reports online 20130608 Pt 7

In the title compound, K(+)·C7H6BrClNO2S(-)·H2O, the K(+) cation is hepta-coordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methyl-benzene-sulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584 (3) Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O-H⋯Br and O-H⋯N hydrogen bonds. ...[more]

PMID: 24046553

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