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Potassium N-bromo-4-chloro-benzene-sulfonamidate monohydrate.


ABSTRACT: In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(-)·H(2)O, the K(+) cation is hepta-coordinated. It is connected to two water O atoms, four sulfonyl O atoms and one Br atom. Further, the sulfonyl and water O atoms in the structure are bridged in a bidentate fashion. The S-N distance of 1.584?(6)?Å is consistent with an S-N double bond, The crystal structure is stabilized by inter-molecular O-H?N hydrogen bonds.

SUBMITTER: Gowda BT 

PROVIDER: S-EPMC3152022 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Potassium N-bromo-4-chloro-benzene-sulfonamidate monohydrate.

Gowda B Thimme BT   Foro Sabine S   Shakuntala K K  

Acta crystallographica. Section E, Structure reports online 20110622 Pt 7


In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(-)·H(2)O, the K(+) cation is hepta-coordinated. It is connected to two water O atoms, four sulfonyl O atoms and one Br atom. Further, the sulfonyl and water O atoms in the structure are bridged in a bidentate fashion. The S-N distance of 1.584 (6) Å is consistent with an S-N double bond, The crystal structure is stabilized by inter-molecular O-H⋯N hydrogen bonds. ...[more]

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