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Potassium N-bromo-2-methyl-benzene-sulfonamidate sesquihydrate.

ABSTRACT: In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(-)·1.5H(2)O, the K(+) ion is hepta-coordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-bromo-2-methyl-benzene-sulfonamide anions. The S-N distance of 1.577?(5)?Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O-H?Br and O-H?N hydrogen bonds.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC3212111 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Potassium N-bromo-2-methyl-benzene-sulfonamidate sesquihydrate.

Gowda B Thimme BT Foro Sabine S Shakuntala K K

Acta crystallographica. Section E, Structure reports online 20110702 Pt 8

In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(-)·1.5H(2)O, the K(+) ion is hepta-coordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-bromo-2-methyl-benzene-sulfonamide anions. The S-N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O-H⋯Br and O-H⋯N hydrogen bonds. ...[more]

PMID: 22090813

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