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Triaqua-(cyclo-hex-4-ene-1,2-dicarboxyl-ato-?O(1))(1,10-phenanthroline-?(2)N,N')cobalt(II).

ABSTRACT: In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo-hexene-1,2-dicarboxyl-ate ligand and three water O atoms in a distorted octa-hedral geometry. The mononuclear mol-ecules are engaged in extensive intra- and inter-molecular O-H?O hydrogen-bonding inter-actions and ?-? stacking inter-actions [centroid-centroid distance = 3.784?(3)?Å], forming a three-dimensional supra-molecular network.

SUBMITTER: Li HY

PROVIDER: S-EPMC3515127 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Triaqua-(cyclo-hex-4-ene-1,2-dicarboxyl-ato-κO(1))(1,10-phenanthroline-κ(2)N,N')cobalt(II).

Li Hai-Ye HY Wang Cheng C Huang Fu-Ping FP Jiang Yi-Min YM

Acta crystallographica. Section E, Structure reports online 20121020 Pt 11

In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo-hexene-1,2-dicarboxyl-ate ligand and three water O atoms in a distorted octa-hedral geometry. The mononuclear mol-ecules are engaged in extensive intra- and inter-molecular O-H⋯O hydrogen-bonding inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.784 (3) Å], forming a three-di ...[more]

PMID: 23284354

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