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Catena-Poly[[[aqua-(2,2'-bipyridine-?(2)N,N')copper(II)]-?-furan-2,5-di-carboxyl-ato-?(2)O(2):O(5)] dihydrate].


ABSTRACT: In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2'-bipyridine) units through a furan-2,5-dicarboxyl-ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl-ate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine mol-ecule is 83.88?(7)°. O(water)-H?O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001).

SUBMITTER: Li YF 

PROVIDER: S-EPMC3515153 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[[aqua-(2,2'-bipyridine-κ(2)N,N')copper(II)]-μ-furan-2,5-di-carboxyl-ato-κ(2)O(2):O(5)] dihydrate].

Li Ya-Feng YF   Xu Yue Y   Qin Xiao-Lin XL   Yuan Yong-Peng YP   Gao Wen-Yuan WY  

Acta crystallographica. Section E, Structure reports online 20121027 Pt 11


In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2'-bipyridine) units through a furan-2,5-dicarboxyl-ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl-ate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine mol-ecule is 83.88 (7)°. O(water)-H⋯O hydrogen bonds connect adjace  ...[more]

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