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Bicyclo-[2.2.1]hept-7-yl p-bromo-benzoate.

ABSTRACT: The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3?(2)°. The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5?(1)°, the methano C atom deviating by 0.141?(2)?Å from this plane. In the crystal, mol-ecules pack as pairs of enanti-omers, with a distance of 3.747?(1)?Å between the centroids of nearest parallel benzene rings.

SUBMITTER: Lloyd BA

PROVIDER: S-EPMC3515191 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Bicyclo-[2.2.1]hept-7-yl p-bromo-benzoate.

Lloyd Barry A BA Arif Atta M AM

Acta crystallographica. Section E, Structure reports online 20121006 Pt 11

The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, mol-ecules pack as pairs of enanti-omers, with a distance of 3.747 (1) Å between the centroids of ...[more]

PMID: 23284418

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