Unknown

Dataset Information

0

Bicyclo-[2.2.1]hept-7-yl p-bromo-benzoate.

ABSTRACT: The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3?(2)°. The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5?(1)°, the methano C atom deviating by 0.141?(2)?Å from this plane. In the crystal, mol-ecules pack as pairs of enanti-omers, with a distance of 3.747?(1)?Å between the centroids of nearest parallel benzene rings.

SUBMITTER: Lloyd BA 

PROVIDER: S-EPMC3515191 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bicyclo-[2.2.1]hept-7-yl p-bromo-benzoate.

Lloyd Barry A BA   Arif Atta M AM  

Acta crystallographica. Section E, Structure reports online 20121006 Pt 11

The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, mol-ecules pack as pairs of enanti-omers, with a distance of 3.747 (1) Å between the centroids of  ...[more]

Similar Datasets

Unknown Bicyclo-[2.2.1]hept-2-en-7-yl 4-bromo-benzoate.
| S-EPMC3394005 | biostudies-literature
Unknown 2-(Bicyclo-[2.2.1]hept-5-en-2-yl)-1H-pyrrolo-[2,3-b]pyridine.
| S-EPMC3006746 | biostudies-literature
Unknown Methyl 2-diphenyl-phosphor-yloxy-2-aza-bicyclo-[2.2.1]hept-5-ene-3-exo-carboxyl-ate.
| S-EPMC2968096 | biostudies-literature
Unknown Gold(I)-Catalyzed Cycloisomerization of 3-Alkoxyl-1,6-diynes: A Facile Access to Bicyclo[2.2.1]hept-5-en-2-ones.
| S-EPMC7318145 | biostudies-literature
Unknown (1S,2S,4R)-7-tert-But-oxy-bicyclo-[2.2.1]hept-5-en-2-yl (2S)-2-(6-meth-oxy-naphthalen-2-yl)propano-ate.
| S-EPMC3151886 | biostudies-other
Unknown N-(3-Amino-bicyclo-[2.2.1]heptan-2-yl)-4-methyl-benzene-sulfonamide.
| S-EPMC3393301 | biostudies-literature
Unknown 2-(4-Bromo-phen-yl)-2-oxoethyl 4-bromo-benzoate.
| S-EPMC3152043 | biostudies-literature
Unknown 3-(2-Bromo-acet-yl)phenyl benzoate.
| S-EPMC3588407 | biostudies-literature
Unknown Methyl 5-bromo-2-[meth-yl(methyl-sulfon-yl)amino]benzoate.
| S-EPMC2977655 | biostudies-literature
Unknown Methyl 4-[N-(5-bromo-pyrimidin-2-yl)carbamo-yl]benzoate.
| S-EPMC3414950 | biostudies-literature